Effect of crystalline morphology on electric and thermal properties of β-polypropylene for HVDC cable insulation
2022 IEEE 4th International Conference on Dielectrics (ICD)(2022)
Abstract
It is widely believed that mechanical and electrical properties of isotactic polypropylene (iPP) can be improved by introducing $\beta$-crystals. But current researches are focused on the influence of $\beta$-crystal content and spherulite size on the properties of iPP. In this paper, the effect of $\beta$-iPP crystal morphology on electrical and thermal properties of iPP used in HVDC cable insulation was studied. A kind of rare earth compounds $\beta$-nucleating agent WBG, which structure is simply expressed as $\left[\mathrm{La}^{3+} \mathrm{Ca}^{2+} \mathrm{P}_{\mathrm{m}} \mathrm{X}_{\mathrm{n}} \mathrm{Q}_{\mathrm{k}}\right]$ was used to generate rich $\beta$-crystalline structure in the compression-molded bars which were fabricated upon different molten temperatures. iPP samples with same crystallinity and $\beta$-crystal percentage but different crystal morphology were obtained. Three types of $\beta$-crystalline morphology, namely, $\beta$-spherulite, $\beta$-transcrystalline entity, and “flower”-like agglomerate of $\beta$-crystallites, were sequentially obtained with increasing molten temperatures (Tf). The morphology, crystallization behavior, DC breakdown strength and thermal property were characterized by polarized optical microscopy (POM), X-ray diffraction (XRD), thermogravimetric analysis (TG). Compared with the sample with $\beta$-spherulite, the DC breakdown strength and 10% weight loss temperature for the sample with “flower”-like agglomerate of $\beta$-crystallites increased by about 8% and 10.9 °C, respectively. The reason for the results may be related to the more fully developed microstructure in “flower”-like agglomerate. It can be concluded that, it is feasible to improve electric and thermal properties of iPP for HVDC cable insulation by introducing special $\beta$-iPP crystal morphology with fully developed microstructure by the method of controlling molten temperatures during the fabricated process.
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Key words
polypropylene,β-crystal,DC breakdown strength,dielectric spectroscopy,thermostability
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