Photodegradation of N-nitrosodimethylamine under 365 nm Light Emitting Diode Irradiation

The photodegradation of NDMA has been extensively investigated under the irradiation of low-pressure or medium-pressure Hg lamps and xenon lamp. However, NDMA photolysis remains unknown under 365 nm ultraviolet light-emitting diode (UV-LED) irradiation. This study conducted a comprehensive investigation on NDMA photodegradation by 365 nm UV-LED illumination. The quantum yield of NDMA photolysis under 365 nm UV-LED irradiation was determined to be 0.0312 +/- 0.0047. The influence of pH on NDMA photodegradation was found to be wavelength dependent. Compared with distilled and deionized water (DDW), tap water inhibited NDMA photodegradation, but secondary wastewater effluent did not. Based on the quantification of NDMA photolysis products and pH influence, the photooxidation of the excited NDMA in the nonprotonated form was proposed to be a major pathway for NDMA photodegradation under the irradiation of UV-LED lamp at 365 nm. This study further enhances our knowledge on NDMA photodegradation. Practitioner Points Quantum yield of NDMA photolysis at 365 nm was determined to be 0.0312 +/- 0.0047. The influence of pH on NDMA photodegradation was wavelength dependent. NDMA photodegradation was inhibited in tap water compared with that in DDW. NDMA photodegradation in SWE was similar to that in DDW. Excited nonprotonated NDMA photooxidation is a major degradation pathway.