Ni‐Catalyzed Cyanation of Allylic Alcohols with Formamide as the Cyano Source

Lin‐Fang Deng, Jing Cheng,Jun‐Jia Chen,Luo Yang

European Journal of Organic Chemistry（2022）

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摘要

Formamide as the safe cyano source! A Ni‐catalyzed cyanation of unactivated allylic alcohols and formamide to provide various α,β‐unsaturated nitriles was developed by generating the cyano unit in situ from safe and readily available formamide.

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关键词

Allylic alcohol,Cyanation• Cyano Source• Formamide,Nickel

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