Chemical stability of 1-substituted 2-aldimine- and 2-azobenzimidazoles under copper-promoted autoxidation

Svetlana E. Korolenko,Elena A. Malinina,Varvara V. Avdeeva,Alexey S. Kubasov,Lyudmila V. Goeva,Elena A. Ugolkova,Vadim V. Minin,Anatolii S. Burlov,Lyudmila N. Divaeva,Nikolay T. Kuznetsov

Inorganica Chimica Acta（2022）

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摘要

•Dimer and polymer Cu(II) complexes are formed in the absence of redox processes.•The Cu(I) complexation was accompanied with redox properties.•Cu(II) complexes with benzimidazole derivatives were synthesized.•The process depends on the solvent used and the nature of the organic ligand.

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关键词

Redox reactions,Copper(II),Benzimidazole derivatives,Electron paramagnetic resonance

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