Mono- and di-deuterated ammonias: Far-infrared spectra and spectroscopic parameters in the ground state

Journal of Molecular Spectroscopy(2022)

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摘要
•NH2D and ND2H transitions are identified in the high resolution far infrared spectra.•For NH2D, 2153 precise transitions in the ground state with J up to 24 are assigned.•For ND2H, 3214 precise transitions in the ground state with J up to 28 are assigned.•Watson-type S reduced Hamiltonian, representations IIIr and IIIl, was adopted.•The model successfully reproduces the transitions at experimental accuracy.
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关键词
NH2D,ND2H,High resolution infrared spectra,Ground state,Watson-type Hamiltonian
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