Iodolium salts as halogen-bond donor catalysts in the Nazarov cyclization: the molecular oxygen enigma
NEW JOURNAL OF CHEMISTRY(2022)
摘要
Cyclic diaryliodonium (e.g. iodolium) salts are effective Lewis-acidic halogen-bond donor catalysts of the Nazarov cyclization. The reaction worked across a series of variously-substituted, activated divinyl ketone precursors, giving the cyclopentenone products in up to 70% isolated yield. Control experiments suggested that air or oxygen were required for catalyst activation and turnover, which constitutes a new, albeit enigmatic, phenomenon in diaryliodonium salt catalysis.
更多查看译文
关键词
Transition Metal Catalysis
AI 理解论文
溯源树
样例
![](https://originalfileserver.aminer.cn/sys/aminer/pubs/mrt_preview.jpeg)
生成溯源树,研究论文发展脉络
Chat Paper
正在生成论文摘要