Iridium-Catalyzed Formal [4+1] Annulation of Benzamides and Cyclopropanols to Afford Isoindolin-1-one Derivatives via C-H Activation
SYNTHESIS-STUTTGART（2022）
Abstract
An iridium-catalyzed reaction protocol has been developed to achieve the oxidative C-H/N-H annulation of benzamides with cyclopropanols as C1 synthon. Structurally diverse isoindolin-1-ones were furnished via sequential C-H/C-C cleavage and C-C/C-N bond formation.
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Key words
C-H activation, benzamides, cyclopropanols, C-N bond formation, isoindolin-1-ones
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