A Photochemoenzymatic Hunsdiecker‐Borodin‐Type Halodecarboxylation of Ferulic Acid

Claudio Zippilli,Miguel Jimenez Bartolome,Thomas Hilberath,Lorenzo Botta,Frank Hollmann,Raffaele Saladino

ChemBioChem（2022）

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摘要

A photochemoenzymatic halodecarboxylation of ferulic acid was achieved using vanadate-dependent chloroperoxidase as (bio)catalyst and oxygen and organic solvent as sole stoichiometric reagents in a biphasic system. Performance and selectivity were improved through a phase transfer catalyst, reaching a turnover number of 660.000 for the enzyme.

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关键词

halodecarboxylation, phase-transfer catalysis, photobiocatalysis, photochemoenzymatic reactions, vanadium chloroperoxidase

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