Comparative effects of the pristine and amino-functionalized metal–organic frameworks on the mechanical properties and microstructures of cement pastes

Ning Yuan,Shanhu Wang,Tianxiang Chen,Xuelu Ma,Huangqi Wang,Xinling Zhang,Dongmin Wang

Construction and Building Materials（2022）

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Abstract

•Pristine and amino-functionalized MIL-101(Fe)-doped cement composites were studied.•Compressive strength can be efficiently increased by adding a small amount of MILs.•Experimental and DFT results demonstrated the in situ formation of Ca-BDC complex.•The enhancement mechanism of doped MILs on cement pastes was proposed in detail.

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Key words

Metal–organic frameworks,Cement-based composites,Mechanical properties,Microstructures,Pore structures

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