A low-polarity small organic molecule with a stable keto form for photocatalytic H-2 evolution
CHEMICAL COMMUNICATIONS(2022)
Abstract
Five small organic molecules (SOMs) with different degrees of enol to keto tautomerism were synthesized for photocatalytic H-2 evolution. The SOM possessing the highest activity features a stable keto form that greatly facilitates the flowing of the excited electrons toward the carbonyl O site where the reduction reaction occurs.
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Key words
small organic molecule,stable keto form,low-polarity
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