Photocatalytic difluoromethylarylation of unactivated alkenes via a (hetero)aryl neophyl-like radical migration
ORGANIC & BIOMOLECULAR CHEMISTRY(2022)
摘要
Photoredox-catalyzed addition of the difluoromethylradical to unactivated alkenes has been found to trigger neophyl-like aryl and heteroaryl migrations which allowed the construction of a diverse series of difluoromethyl ketones. The reaction featured mild reaction conditions and broad substrate scope.
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关键词
photocatalytic difluoromethylarylation,unactivated alkenes,migration,neophyl-like
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