Highly in-plane anisotropic optical properties of fullerene monolayers

Both the intrinsic anisotropic optical materials and fullerene-assembled 2D materials have attracted much interest in fundamental science and potential applications. The synthesis of a monolayer (ML) fullerene makes the combination of these two features plausible. In this work, using first-principles calculations, we systematically study the electronic structure and optical properties of quasi-hexagonal phase (qHP) ML and quasi-tetragonal phase (qTP) ML fullerenes. The calculations of qHP ML show that it is a semiconductor with small anisotropic optical absorption, which agrees with the recent experimental measurements. However, the results for qTP ML reveal that it is a semimetal with highly in-plane anisotropic absorption. The dichroic ratio, namely the absorption ratio of x - and y -polarized light α xx / α yy , is around 12 at photon energy of 0.29 eV. This anisotropy is much more pronounced when the photon energy is between 0.7 and 1.4 eV, where α xx becomes nearly zero while α yy is more than two orders of magnitude larger. This indicates qTP ML as a candidate for long-pursuit lossless metal and a potential material for atomically thin polarizer. We hope this will stimulate further experimental efforts in the study of qTP ML and other fullerene-assembled 2D materials.