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Embedding ZnCdS@ZnIn2S4 into thiazole-modified g-C3N4 by electrostatic self-assembly to build dual Z-scheme heterojunction with spatially separated active centers for photocatalytic H2 evolution and ofloxacin degradation

Separation and Purification Technology(2022)

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摘要
•The dual Z-scheme heterojunction improves the separation and migration efficiency of electron-hole pairs.•The space separation between the oxidation center and the reduction center improves the utilization rate of carriers.•Thiazoles as an electron acceptor to reconstruct electrons on the g-C3N4 surface and adjust its HOMO and LUMO dispersion to improve electron mobility.•ZnCdS@ZnIn2S4@g-C3N4-vTA prepared by electrostatic self-assembly, and its intimate interfacial contact shortens the migration distance of carriers.
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关键词
Dual Z-scheme heterojunction,Electrostatic self-assembly,Molecular engineering,Photocatalytic H2 evolution,Ofloxacin degradation
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