Effect of dilution on the performance of ionic liquids in milliflow solvent extraction applications: Towards integration of extraction, scrubbing and stripping operations with in-line membrane-based phase separation

Separation and Purification Technology(2022)

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摘要
•Loss of secondary slug flow recirculations can be avoided by ionic liquid dilution.•Balancing of mass-transfer and reaction-limitations by IL concentration modulation.•Improved extraction selectivity, reagent use and slug flow stability upon dilution.•In-line membrane-based phase separation up to 65 vol% [A336][HSO4] in p-cymene.•Integration of millifluidic Ge(IV) solvent extraction, scrubbing and stripping.
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关键词
Aliquat 336,Flow chemistry,Germanium,Hydrodynamics,Mass transfer,Process intensification,Slug flow,Solvent extraction
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