Fluorinated phosphonium salts and ionic liquids prepared via thiol-ene click chemistry: a physical and thermal property study

Alexis E. Langtry,Kaitlyn B. Thompson,Neil D. Redeker,Ashlee S. Quintana, Denise L. Bui,Kevin T. Greeson,Nicolas Cena,Jacob C. Marcischak,Levi M. J. Moore,Kamran B. Ghiassi

Journal of Molecular Liquids（2022）

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摘要

•Synthesis of 18 fluorinated phosphonium salts using thiol-ene click chemistry.•14 of the salts are ionic liquids (ILs), 5 are liquids at room-temperature (RTILs)•2 ILs show supercooling behavior, eventually solidifying over time.•Several ILs show interesting thermal behavior, possibly due to domain segregation.•X-ray crystal structure shows segregation between fluorous and non-fluorous domains.

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关键词

Ionic liquid,Phosphonium cation,Fluorinated cation,Thiol-ene click,Crystal structure,DSC

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