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An unsymmetrical mixed-valence oxidovanadium(IV/V) binuclear complex: Synthesis, characterization, DFT studies, and bromoperoxidase activity

Rubia C. R. Bottini,Lucas G. Fachini,Gabriel B. Baptistella,Danilo Stinghen,Francielli S. Santana,Matteo Briganti,Ronny R. Ribeiro,Jaisa F. Soares,Eduardo L. Sa,Giovana G. Nunes

Inorganica Chimica Acta（2022）

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Abstract
•An unsymmetrical mixed-valence oxidovanadium(IV/V) binuclear complex was synthesized.•DFT calculations and EPR spectroscopy indicates a localized mixed-valence.•The bromoperoxidase activity using the phenol red was evaluated.
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Key words
Mixed-valence,Oxidovanadium,Binuclear,Unsymmetrical,DFT,Bromination
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