Spin crossover in iron(II) complexes with new ligand 2,6-bis(4,5-dimethyl-1H-imidazole-2-yl)pyridine

Alina D. Ivanova,Evgeniy Korotaev,Vladislav Yu Komarov,Taisiya S. Sukhikh,Svetlana Trubina,Liliya A. Sheludyakova,Sergey A. Petrov,Alexsei Ya Tikhonov,Lyudmila G. Lavrenova

Inorganica Chimica Acta（2022）

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Abstract

Iron(II) complexes with new ligand 2,6-bis(4,5-dimethyl-1H-imidazole-2-yl)pyridine possessing a high-temperature 1A1 ↔ 5T2 spin crossover were obtained.

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Key words

Iron(II) complexes,2,6-bis(4,5-dimethyl-1H-imidazol-2-yl)pyridine,EXAFS spectroscopy,Mössbauer spectroscopy,Spin crossover,Crystal structure

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