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Effects of inorganic sulfur species on hydrocarbon conversion and 34S isotope fractionation during thermal maturation of Type II kerogen

Kun He,Shuichang Zhang,Xiaomei Wang,Qisheng Ma, Zhen Li,Donald E. Canfield,Jingkui Mi,Yongchun Tang

Organic Geochemistry（2022）

Cited 2|Views25
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Abstract
•TSR accelerated oil and hydrocarbon gas decompositions in the pyrolysis of OM.•Pyrite decomposition was responsible for the 34S-depletion of H2S at 330–450 °C.•TSR led to the enrichment in 34S of H2S and oils in thermal maturation of OM.•Two parts of 34S fractionation by KIE and 34S exchange were observed for TSR.
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Key words
Sulfur isotope fractionation,Kinetic isotope effect,Equilibrium isotope effect,Sulfate,Pyrite
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