Synthesis of the Porous ZnO Nanosheets and TiO2/ZnO/FTO Composite Films by a Low-Temperature Hydrothermal Method and Their Applications in Photocatalysis and Electrochromism

In this paper, porous zinc oxide (ZnO) nanosheets were successfully prepared by a simple low-temperature hydrothermal method. X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and Brunauer-Emmett-Teller (BET) tests showed that the synthesized product was ZnO with porous sheet structure. The diameter of porous nanosheets was about 100 nm and the thickness was about 8 nm. As a photocatalyst, the degradation efficiencies of porous ZnO nanosheets for methyl orange (MO), methylene blue (MB) and Rhodamine B (RhB) were 97.5%, 99% and 96.8%, respectively. In addition, the degradation efficiency of ZnO for mixed dyes (Mo, MB and RhB) was satisfactory, reaching 97.7%. The photocatalytic stability of MB was further tested and remained at 99% after 20 cycles. In the experiment, ZnO/FTO (fluorine-doped tin oxide) composites were prepared by using ZnO as the conductive layer. Titanium dioxide (TiO2) was deposited on the surface of ZnO/FTO by electrodeposition, so as to obtain a TiO2/ZnO/FTO composite. By studying the electrochromic properties of this composite, it was found that the TiO2/ZnO/FTO composite shows a large light modulation range (55% at 1000 nm) and excellent cycle stability (96.6% at 200 cycles). The main reason for the excellent electrochromic properties may be the synergistic effect between the porous structure and the polymetallic oxides. This study is helpful to improve the photocatalytic efficiency and cycling stability of metal oxides, improve the transmittance of thin films and provide a new strategy for the preparation of ZnO composite materials with excellent photocatalytic and electrochromic properties.