Cobalt supported on biomass carbon tubes derived from cotton fibers towards high-efficient electrocatalytic overall water-splitting

Developing noble-metal-free electrocatalysts for high-efficiency oxygen evolution reaction (OER) and hydrogen evolution reaction (HER) is still a challenge in the energy conversion application. Herein, a new bifunctional electrocatalyst Co/BCTs is exploited via in-situ growth of metallic Co particles on/in the surface of biomass carbon tubes (BCTs) derived from available natural cotton fibers, which exhibits the outstanding electrocatalytic performance for OER, HER and overall water-splitting. It is because that the mordification effect of Co particles improves conductivity, facilitates electron transfer and activates surface of BCTs, and meanwhile the unique micro-structure and morphology of Co/BCTs can promote the molecular mass transport and shorten the molecular diffusion distance. As expected, the electrolyzer assembled by Co/BCTs-5 as electrode couple attains a very low potential of 1.40 V at 10 mA cm(-2) for overall water splitting in alkaline electrolyte. This work endows new opportunities and potential values for exploiting the high-efficiency noble-metal-free electrocatalysts originated from natural biological derived materials. (C) 2022 Elsevier Ltd. All rights reserved.