Supramolecular Chiral Assembly of Symmetric Molecules with an Extended Conjugated Core
ACS APPLIED MATERIALS & INTERFACES(2022)
Abstract
C-3-symmetric molecules carrying a conjugated diacetylene (DA) core are found to self-assemble into well-defined supramolecular fibers with enhanced supramolecular chirality in both organic and aqueous solutions. The conjugated core affords these amphiphiles characteristic fluorescence properties, which can be quenched partially due to the aggregation. Integration of the C-3-symmetry with the conjugation provides these novel molecules strong aggregation tendency through solvent-mediated pi-pi stacking with preferential supramolecular chirality, which is predominately related to steric hindrance from their dipeptide pendants. Highly uniform supramolecular fibers of P and M handedness with thickness consistent in the dimensions of individual C-3 molecules are obtained. The increase of concentrations induces these fibers to wrap together to form supramolecular fibrous bundles. Topochemical polymerization of the DA moieties can transform these supramolecular fibers into stable covalent polymers. We therefore believe that self-assembly of these C-3-symmetric molecules with extended conjugated DA cores provides new prospects for the construction of supramolecular helical fibers through enhanced pi-pi stacking and creates a convenient strategy to furnish covalent chiral polymers of hierarchical structures through supramolecular assembly.
MoreTranslated text
Key words
supramolecular assembly,helical conformation,supramolecular chirality,pi-pi stacking,topochemical polymerization
AI Read Science
Must-Reading Tree
Example
![](https://originalfileserver.aminer.cn/sys/aminer/pubs/mrt_preview.jpeg)
Generate MRT to find the research sequence of this paper
Chat Paper
Summary is being generated by the instructions you defined