A chiral 3D silver(i)-benzenedithiolate coordination polymer exhibiting photoemission and non-linear optical response

Saly Hawila,Ahmad Abdallah,Jean-Luc Rukemampunzi,Alexandra Fateeva,Gilles Ledoux,Régis Debord, Stéphane Paihlès,Nathalie Guillou,Florian Massuyeau,Romain Gautier,Adel Mesbah,Aude Demessence

CHEMICAL COMMUNICATIONS（2022）

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摘要

A new tridimensional metal-organic chalcogenolate, made of a 1,3-benzenedithiolate bridging ligand and Ag(i), [Ag-2(1,3-BDT)](n), is reported. This coordination polymer has good thermal stability in air and displays both photoluminescence properties and a second harmonic generation response.

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