Pictet-Spengler Reaction for the Chemical Synthesis of Strictosidine.

Yingchao Dou,Laurent Evanno,Erwan Poupon,Guillaume Vincent

Methods in molecular biology (Clifton, N.J.)（2022）

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摘要

Strictosidine is the common biosynthetic precursor of Monoterpene Indole Alkaloids (MIA). A practical single-step procedure to assemble strictosidine from secologanin is described via a bioinspired Pictet-Spengler reaction. Mild conditions and purification by crystallization and flash chromatography allow access to the targeted product in fair yield.

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关键词

Chemical synthesis,Pictet–Spengler,Secologanin,Strictosidine,bioinspired method

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