Visible-Light-Induced Copper-Catalyzed Asymmetric C(sp3)–C(sp3)–H Glycosylation: Access to C‑Glycopeptides
Organic Letters(2022)
摘要
Herein, a practical and highly efficient method for visible-light-induced copper-catalyzed N-aminoquinoline-directed asymmetric C(sp3)–C(sp3)–H glycosylation was reported. At the same time, C(sp3)–C(sp3)–H glycosylation of nondeoxysugars with amino acids to construct C-glycopeptides was achieved. This approach promoted the synthesis of various C-glycopeptides and provided a new model for the synthesis of C-glycoamino acids.
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关键词
glycosylation,visible-light-induced visible-light-induced,copper-catalyzed,c-glycopeptides
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