Degradation of Li3V2(PO4)3-based full-cells containing Li4Ti5O12 or Li3.2V0.8Si0.2O4 anodes modeled by charge-discharge cycling simulations

•Cycling performance of two Li3V2(PO4)3-based full-cell types is evaluated.•Cell degradation is analyzed using charge–discharge simulations and experiments.•Full cells with high-potential Li4Ti5O12 anode are degraded by low anode CE.•Full cells with low-potential Li3.2V0.8Si0.2O4 anode are degraded by anode capacity decay.•Simulations are applicable to the study of cell degradation of a wide range of electrodes.