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Soluble, crystalline, and thermally stable alkali CO2− and carbonite (CO22−) clusters supported by cyclic(alkyl)(amino) carbenes

Lucas A. Freeman,Akachukwu D. Obi,Haleigh R. Machost,Andrew Molino,Asa W. Nichols,Diane A. Dickie,David J. D. Wilson,Charles W. Machan,Robert J. Gilliard

Chemical Science（2021）

Cited 6|Views4
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Abstract
The direct chemical reduction of CAACCO2 adducts by alkali metals to yield multinuclear clusters is reported. The mono- and dianions of CO2 have been studied for decades and are fundamentally important oxycarbanions and critical species in CO2 fixation chemistry.
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