The unexpected reactivity of 9-iodo-nido-carborane: from nucleophilic substitution reactions to the synthesis of tricobalt tris(dicarbollide) Na[4,4′,4′′-(MeOCH2CH2O)3-3,3′,3′′-Co33-O)(μ3-S)(1,2-C2B9H10)3]

Dalton Transactions(2021)

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摘要
An unusual reactivity of 9-iodo-nido-carborane [9-I-7,8-C2B9H11]− towards nucleophiles under strong basic conditions was revealed.
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关键词
nucleophilic substitution reactions,synthesis,unexpected reactivity
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