A new twist on an old ligand: a [Mn₁₆] double square wheel and a [Mn₁₀] contorted wheel

Thomais G. Tziotzi,Marco Coletta,Mark Gray,Cameron L. Campbell,Scott J. Dalgarno,Giulia Lorusso,Marco Evangelisti,Euan K. Brechin,Constantinos J. Milios

Inorganic Chemistry Frontiers（2021）

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摘要

The use of 1,3,5-tri(2-hydroxyethyl)-1,3,5-triazacyclohexane (LH3) in manganese cluster chemistry leads to the synthesis of a {Mn16} double square wheel and a {Mn10} contorted wheel.

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A new twist on an old ligand: a [Mn16] double square wheel and a [Mn10] contorted wheel

A new twist on an old ligand: a [Mn₁₆] double square wheel and a [Mn₁₀] contorted wheel