Numerical Simulation of the Burning Process in a King-Size Cigarette Based on Experimentally Derived Reaction Kinetics

Summary A comprehensive two-dimensional (2D) mathematical model has been proposed to simulate the burning process of a king-size cigarette. The characteristics of this model are including: 1) the use of kinetic models for the evaporation of water, the pyrolysis of tobacco and the oxidation of char, 2) the application of mathematical relationships between the release amounts of certain products (i.e., “tar” and CO) and different reaction variables (i.e., temperatures and oxygen concentrations), 3) the introduction of mass, heat and momentum transports, 4) the consideration of filtration effects of the cigarette filter on “tar”. These characteristics were expressed in a set of coupled equations that can be solved numerically by FLUENT. The information about the char density field, temperature field, flow velocity field, “tar” and CO density fields and the filtration efficiency could be obtained from the model. This model was validated by comparing the predictions with experimental data on puff number, the temperatures at specific locations, the filtration efficiency and the yields of “tar” and CO under different puff intensities. The calculated results show a good agreement with the experimental data. The predicted puff number was 7.3, and the experimental puff number was 6.8. The standard root mean square error (NRMSE) between the experimental and the predicted temperatures at specific locations is < 18%. The predicted filtration efficiency for “tar” was 46.1%, and the experimentally determined filtration efficiency for nicotine was 44.5%. The maximum relative deviations of the yields of “tar” and CO under different puff intensities were 8.9% and 10.6%, respectively.