A dithizone-anchored silica gel surface, {SiO₂}@DZ for the selective sample cleanup of Gd(iii) amidst Fe(iii), Th(iv), and Ce(iv) employing ion pair complexation

Rimi Sarkar,Sneha Mondal,Biswajit Hansda,Mousumi Chatterjee,Bhabatosh Mandal

New Journal of Chemistry（2021）

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摘要

Sorption–desorption equilibration, {extractor-HOMO}:{H3O}+ + {metal-species}n+ ⇄ {extractor-HOMO}:{metal-species}n+ + {H3O}+, an eventual ion-pair complexation controlled by {H3O}+.

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A dithizone-anchored silica gel surface, {SiO2}@DZ for the selective sample cleanup of Gd(iii) amidst Fe(iii), Th(iv), and Ce(iv) employing ion pair complexation

A dithizone-anchored silica gel surface, {SiO₂}@DZ for the selective sample cleanup of Gd(iii) amidst Fe(iii), Th(iv), and Ce(iv) employing ion pair complexation