Magnesium Hemithioacetate

[2568582-50-1] C8H7BrMgOS (MW 255.41) InChI = 1S/C8H7OS.BrH.Mg/c9-8-7-4-2-1-3-6(7)5-10-8;;/h1-4,8H,5H2;1H;/q-1;;+2/p-1 InChIKey = OUGQRXIEPHEJJN-UHFFFAOYSA-M [2568582-53-4] C4H9BrMgOS (MW 209.38) InChI = 1S/C4H9OS.BrH.Mg/c1-3-6-4(2)5;;/h4H,3H2,1-2H3;1H;/q-1;;+2/p-1 InChIKey = AUCXBAZMMNOTSH-UHFFFAOYSA-M (stereoselective reduction of NAD+ model1) Physical Data: not isolated; prepared in situ. Solubility: sol THF, DMF. Preparative Methods: the standard preparation involves the reaction of hemithioacetal with MeMgBr in THF at 0 °C. Handling, Storage, and Precautions: highly air and water sensitive. Should not be isolated.