Synthesis and characterisation of an enantiomerically pure scandium pentadienyl complex and its application in the polymerisation of rac-lactide

Katharina Münster,Jan Raeder,Marc D. Walter

Dalton Transactions（2022）

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摘要

An enantiomerically pure constrained geometry scandium complex featuring a pentadienyl moiety was synthesised. The complex efficiently catalyses the polymerisation of rac-lactide to give slightly heterotactic, amorphous poly-(lactide).

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