Wheel-like Gd₄₂ polynuclear complexes with significant magnetocaloric effect

Zi-Wei Che,Ji-Tun Chen,Tian-Tian Wang,Han Yan,Teng-Da Zhou,Rui Guo,Wen-Bin Sun

CrystEngComm（2022）

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摘要

Two 42-nuclearity lanthanide complexes with a wheel-like structure were synthesized, in which Gd congeners exhibited a significant magnetocaloric effect due to the high isotropy Gd nuclearity and weak ferromagnetic interactions.

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Wheel-like Gd42 polynuclear complexes with significant magnetocaloric effect

Wheel-like Gd₄₂ polynuclear complexes with significant magnetocaloric effect