Thermal initiation and propagation of the decomposition process
Theoretical and Computational ChemistryMolecular Modeling of the Sensitivities of Energetic Materials(2022)
摘要
This chapter reviews sensitivity correlations assuming initiation to be thermal in nature. A first group focuses on the thermal onset of chemistry, either considering only the first bond breaking events or accounting for more details of the mechanism. A second group assigns a prominent role to the propagation of the decomposition. Finally, a two-states model predicting the initiation probability as a function of the magnitude of the load is outlined.
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关键词
thermal initiation,decomposition,process
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