Suppressing oxygen vacancies on the surface of Li-rich material as a high-energy cathode via high oxygen affinity Ca0.95Bi0.05MnO3 coating

Xueqian Ji,Yuxing Xu, Yuncheng Zhou,Jiechen Song, Hailan Feng,Pengfei Wang, Jun Yang,Fuchang Zhuge, Haijiao Xie,Qiangqiang Tan

Electrochimica Acta(2022)

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摘要
•The high oxygen affinity material coating Li-rich cathodes is proposed.•The formation energy of oxygen vacancies and the stability of lattice oxygen are enhanced.•The voltage decay of modified materials is suppressed.•Li-rich cathodes deliver excellent cycling stability, stable voltage, and rate performance.
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关键词
Lithium-ion batteries,Li-rich materials,Surface modification,Multifunctional coating layers,Oxygen redox reactions
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