Mixed-metal calix[8]arene complexes: structure, and ring opening polymerisation studies

Tian Xing,Max Derbyshire,Mark R J Elsegood,Carl Redshaw

Chemical Communications（2022）

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摘要

Reactions of différent combinations of group V alkoxides or tungsten oxyalkoxide salts with p-tert-butylcalix[8]areneH8 (L8H8) affords mixed-metal calix[8]arene systems. Intruiging molecular structures are formed and the systems are capable of the ring opening polymerisation of ε-caprolactone under N2, air, or as melts affording mostly low molecular weight products.

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