Co3O4/4A分子筛活化PMS处理高盐AO7废水研究
Technology of Water Treatment(2022)
Abstract
采用浸渍-焙烧法制备Co3O4/4A分子筛复合催化剂,用于活化过一硫酸盐(PMS)处理高盐酸性橙7(AO7)废水.采用扫描电镜、X-射线衍射仪、红外光谱仪等对复合催化剂进行表征,同时考察其稳定性.考察复合催化剂活化PMS对AO7模拟废水的处理效果,结果表明,当Co3O4/4A分子筛投加量为0.2 g/L、PMS投加量为0.7 mmol/L、pH为9时,高盐(Na2SO4,10 g/L)废水中AO7浓度可在20 min内由15 mg/L左右降至接近0,去除率达99%以上,同时催化剂钴离子溶出量约为0.36 mg/L,低于《地表水环境质量标准》(GB3838-2002)中规定的1000 μg/L.
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