Highly elastic aerogel derived from spent coffee grounds as oil removal adsorbent
Korean Journal of Chemical Engineering(2022)
Abstract
In the face of increasing environmental pollution, aerogels have emerged as valuable materials for potential oil/water separation. However, many of the currently developed aerogels have unsatisfactory compressibility, high cost and a single hydrophobic modification method, which limits larger-scale application. In this work, a type of aerogel with compressible, inexpensive, and fully biodegradable features was designed via a novel zirconium chloride modification strategy. Typically, a series of aerogels (HCSW-1, HCSW-2, and HCSW-3) were readily prepared from a mixture of spent coffee grounds, waste paper and sodium alginate. The prepared aerogels exhibited good elasticity, low density (0.024 g cm −3 ), high porosity (98.3%), efficient oil/water separation and good oil uptake (23-44 times of its weight). In addition, the as-prepared aerogels can be easily recycled several times, thus meeting the demand of actual oil/water separation. Such prominent results provide a new perspective for the development of efficient hydrophobic aerogels in the treatment of offshore oil spills and industrial wastewater.
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Key words
Bio-based Aerogel, Spent Coffee Grounds, Hydrophobic Modification, Oil/Water Separation
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