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Directing group enabled ‘On-Water’ CH bond functionalization of ferrocene derivatives

Ashutosh Verma,Pritam Dolui,Susanta Hazra,Anil J. J. Elias

Journal of Organometallic Chemistry（2022）

Cited 7|Views4
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Abstract
•First ‘on-water’ procedure for the CH bond functionalization of the cyclopentadienyl ring of ferrocene.•8-aminoquinoline and picolinamide were used as the directing groups.•Reactions were carried out in aqueous medium under air and reusability of catalyst and solvent were shown.•Control experiments carried out indicates in situ formation of palladacycles.
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Key words
‘On-water’ reaction,Bis C-H bond functionalization,Bidentate-directing groups,Ferrocene,reusability,Greener pathway
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