Bimetallic MxRu100−x nanoparticles (M = Fe, Co) on supported ionic liquid phases (MxRu100−x@SILP) as hydrogenation catalysts: Influence of M and M:Ru ratio on activity and selectivity
Journal of Catalysis(2022)
摘要
•Versatile synthesis of bimetallic MxRu100−x@SILP (M = Fe, Co) catalysts.•Systematic comparison of catalytic performances in hydrogenation.•Activity and selectivity depend on the M:Ru ratios, with clear synergistic effects.•For a given selectivity, CoxRu100−x more active than FexRu100-x while requiring less Ru.•Crucial influence of the nature of the “diluting” 3d metal.
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关键词
Bimetallic nanoparticles,SILP,Ruthenium,Iron,Cobalt,Catalytic hydrogenation,Synergistic effect
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