DART Mass Spectrometry in the Analysis of Organometallic Complexes

S. V. Goryainov,C. Esparza,L. N. Kulikova, A. R. Borisova, P. A. Kumandin,A. S. Antonova,E. O. Rystsova, M. T. Oshakbaev, G. T. Omarova,N. Yu. Polovkov

JOURNAL OF ANALYTICAL CHEMISTRY(2021)

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摘要
We recorded and interpreted DART mass spectra of Hoveyda–Grubbs catalysts with N→Ru and S→Ru coordination bonds. The set of ions formed under DART ionization conditions is similar to those obtained using matrix-assisted laser desorption/ionization mass spectrometry. The optimal conditions (ionization gas, gas flow temperature) for recording DART mass spectra of the studied compounds were determined.
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关键词
mass spectrometry, DART, organometallic complexes, Grubbs catalysts
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