DART Mass Spectrometry in the Analysis of Organometallic Complexes
JOURNAL OF ANALYTICAL CHEMISTRY(2021)
Abstract
We recorded and interpreted DART mass spectra of Hoveyda–Grubbs catalysts with N→Ru and S→Ru coordination bonds. The set of ions formed under DART ionization conditions is similar to those obtained using matrix-assisted laser desorption/ionization mass spectrometry. The optimal conditions (ionization gas, gas flow temperature) for recording DART mass spectra of the studied compounds were determined.
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Key words
mass spectrometry, DART, organometallic complexes, Grubbs catalysts
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