Nature of HCl oxidation Au anomalies and activation of non-carbon-material-supported Au catalyst

Bolin Wang,Yuxue Yue,Xiangxue Pang,Mingde Yu,Ting Wang,Renqin Chang,Zhiyan Pan,Jia Zhao,Xiaonian Li

Journal of Catalysis（2021）

引用 10|浏览8

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摘要

•Inactive Au/TiO2 can be activated by Cl radicals.•Once Cl is consumed, the reaction will be terminated, although a large amount of supported cationic Au remains.•The Au(I)–Au(III) redox couple is responsible for triggering the reaction.

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关键词

Supported cationic gold,Au/TiO2,Au(I)–Au(III) redox couple,Cl radicals,Vinyl chloride

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