Efficient UO22+ extraction by DAPhens with asymmetric terminal groups: The molecular design, spectral titration, liquid-liquid extraction and mechanism study

Haolong Wang, Tengfei Cui,Jixue Sui,Pavle Mocilac,Yin Wang,Zhijun Guo

Separation and Purification Technology（2022）

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摘要

•DAPhens with asymmetric terminal groups show high selectivity to UO22+.•Methyl groups in amide moieties facilitate DAPhens’ extraction performance.•Less distortion of DAPhens in complex benefits its superior affinity to UO22+.

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关键词

Solvent extraction,DAPhens,Uranyl separation,Steric hindrance,Single-crystal structure

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