Effect of Chloride on the Pitting Corrosion of Carbon Steel in Alkaline Solutions

The effect of chloride concentration on the passivity breakdown of carbon steel in deaerated pH = 13.5 alkaline solution was investigated. The results show that chloride plays an important role for the pitting corrosion of carbon steel. When NaCl <= 1 M, the carbon steel is passive but for 1 M< NaCl <= 2 M, the carbon steel transfers from passive to passivity breakdown. When NaCl >= 2 M, passive film breakdown occurs and the passivity breakdown potential (E-b) of carbon steel is linearly-dependent on the logarithm of the chloride activity in the alkaline solution. As predicted by the PDM, the near-normal distribution of E-b is well indicated by the near straight line in the cumulative distribution probability. The analysis in this study gives us a method to calculate the E-b of carbon steel in alkaline solution and its distribution for any given chloride concentration. (C) 2022 The Electrochemical Society ("ECS"). Published on behalf of ECS by IOP Publishing Limited.