The isomeric effect on the D-pi-pi-A prototype fluorescent material: synthesis, photophysical property, and computation
MONATSHEFTE FUR CHEMIE(2021)
摘要
Two novel organic fluorescent isomers with D-pi-pi-A prototype structure, namely, (E)-2-[3-([1,1'-biphenyl]-4-yl)-1-(6-methoxynaphthalen-2-yl)allylidene]malononitrile and (E)-2-[1-([1,1'-biphenyl]-4-yl)-3-(6-methoxynaphthalen-2-yl)allylidene]malononitrile, were synthesized. Due to the exchange of naphthalene and biphenyl moieties on each side of conjugated bridge (C = C(CN)(2))-conjugated bridge (C = C) group, two compounds are organic fluorescent isomers, and display different molecular stacking mode and photophysical property. Molecules of (E)-2-[3-([1,1'-biphenyl]-4-yl)-1-(6-methoxynaphthalen-2-yl)allylidene]malononitrile are packed with H-aggregation, while (E)-2-[1-([1,1'-biphenyl]-4-yl)-3-(6-methoxynaphthalen-2-yl)allylidene]malononitrile has a J-aggregation. Both of two compounds show solvatochromism and tunable aggregation-induced enhanced emission property. [GRAPHICS] .
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关键词
Isomeric effect, Organic fluorescent, Photophysical property
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