Kinetics of acid blue 40 dye degradation under solar light in the presence of CuO nanoparticles synthesized using Citrullus lanatus seeds extract

ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-INTERNATIONAL JOURNAL OF RESEARCH IN PHYSICAL CHEMISTRY & CHEMICAL PHYSICS(2022)

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Abstract
In view of eco-benign nature of green synthesis, in the present investigation, the CuO NPs are prepared using Citrullus lanatus seeds extract and photocatalytic degradation efficiency for Acid Blue 40 (AB-40) was evaluated. The CuO NPs were characterized by XRD (X-ray diffraction), SEM (scanning electron microscopy), EDX (energy dispersive X-ray), and FT-IR (Fourier transform infrared) techniques. The synthesized CuO NPs was in face centered monoclinic crystalline form with particle size in 40-60 nm range. The photocatalytic degradation potential of CuO NPs was assessed for acid blue 40 (AB-40) dye degradation and catalyst dose, concentration of dye, radiation exposure time and pH are considered for dye removal. The CuO NPs exhibited auspicious efficiency, an 84.89% dye removal was attained at optimal conditions and dye degradation followed BMG (Behnajady-Modirshahla-Ghanbery) kinetics model. Results revealed CuO NPs synthesized using C. lanatus seeds extract is photoactive catalyst and green route can be employed for CuO NPs fabrication for photocatalytic applications.
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Key words
acid blue 40, CuO NPs, green synthesis, kinetics, photocatalysis, solar light irradiation
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