Syntheses and structures of two new inorganic-organic hybrid nickel vanadates [Ni(H2biim)3]V2O6 and [Ni(H2biim)3][(VO2)(SO4)] (H2biim=2,2′-biimidazole)

Journal of Molecular Structure(2022)

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摘要
•Hydrothermal synthesis of two novel bimetallic vanadium compounds.•The hybrid materials constructed from {VO3-}n and {V-O-S}n chains linked through the metal–organic units.•The anion SO42- acts played an important role in the building unit of compound 2.•Compound 2 exhibited the fluorescence properties.
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关键词
Nickle bimetallic complexes,Bi-imidazole ligand,Hydrothermal synthesis,Inorganic–organic hybrid materials,Vanadium oxide-sulfur chain
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