Selective adsorption and separation of Cu(II) from Zn solution by CU resin

Journal of Radioanalytical and Nuclear Chemistry(2022)

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摘要
The aim of present study was to determine the efficiency of CU selective resin for separation of radionuclides Cu from large excess of Zn. Adsorption behaviors towards Cu 2+ ions was investigated as function of solution pH, contact time, Cu 2+ concentration, Zn 2+ concentration, amount of CU resin, the effect of coexisting cation ions and the irradiation stability of CU resin. A stronger binding propensity towards Cu 2+ ions over Zn 2+ and excellent radiation resistance of CU resin were found, which endowed that this CU resin is capable of effectively separating radioisotopes Cu. Moreover the good separation of Cu 2+ has been achieved from bulky Zn 2+ using column chromatography separation. In general, the present research has confirmed the great potential application of CU resin as a more efficient column chromatography material for the separation of medical radioisotopes Cu from irradiated Zn targets.
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关键词
Chemical separation, Adsorption selectivity, Cu2+ , Zn2+ , Column chromatography
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