Synthesis of Dialkyl-Diphosphenes and -Distibenes that Bear Extended Triptycyl Groups

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN（2021）

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摘要

Dialkyl-diphosphenes and -distibenes of the type RTrp*E-2(2) (E = P, Sb; R = H, n-Pr) were synthesized and isolated using the steric protection of extended triptycyl groups (Trp*). The solubility of these diphosphenes and distibenes can be increased by installing a propyl group onto the bridgehead position of the triptycyl core (n-PrTrp*).

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关键词

Dipnictene, Steric protection, X-ray analysis

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