Genesis of an Fe5C2@Fe3O4 core/shell structure during CO carburization of metallic iron nanoparticles

Journal of Catalysis(2022)

引用 6|浏览7
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摘要
•a time- and space-resolved iron carbide-oxide Fe5C2@Fe3O4 core–shell structure.•NAP-XPS and ETEM uncovering of phase transformation of a metallic iron catalyst exposed to carbon monoxide.•role of iron carbides in FTS chain growth and Fe3O4 overlayer in the water–gas shift reaction.
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关键词
Iron carbide-oxide Fe5C2@Fe3O4 core–shell structure model,In situ NAP-XPS and,ETEM FTS chain growth and water–gas shift reaction iron catalyst stability and CO2,Selectivity mitigation
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